I have experienced the same after long duration SV cooking.
This is from MC 2,214:
"Although most sealing problems are merely annoyances, a bad odor coming from a bag when it is opened should be a big concern. Bad odors can be a signal that bacterial growth has occurred during storage or cooking. Because some bacteria generate dangerous toxins, promptly discard any food in bags that smell bad when opened. Similarly, bags puffing up over time while cold may be a symptom of bacterial growth inside."