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Caramelization happen at lower temperature in a basic environment. So by putting baking soda you raise the ph of your product (More basic) and facilitate the caramelization. The pressure cooker also raise the boiling temperature of the water so that you can reach the new lower caramelization temperature. If you want to see the effect clearly. Put three mason jars in your pressure cooker. One with baking soda, one with lemon juice and the third one with nothing. You'll see the difference.

Good luck

Louis-Frederic

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