Are you sure you placed the cocoa butter side down? I'm not suggesting you wouldn't know better, but you never know, sometimes it is hard to tell which way is up w/o touching the surface to feel for pattern. I admit that I have done this on an occassional piece in the midst of a long, monotonous dipping session. Otherwise, unless you waited a while after dipping (or did not reheat the chocolate a bit after achieving a temper, I know some pastry chefs who do this), the cocoa butter definitely should have come off. I also presume you had the transfer sheet at room temperature, not chilled.